{"id":15140,"date":"2022-12-05T03:21:48","date_gmt":"2022-12-12T02:17:54","guid":{"rendered":"https:\/\/www.htech360.com\/?p=15140"},"modified":"2022-12-12T10:54:17","modified_gmt":"2022-12-12T02:54:17","slug":"c964a60557","status":"publish","type":"post","link":"https:\/\/www.htech360.com\/a\/15140","title":{"rendered":"\u6e05\u534e\u5927\u5b66 | \u9ad8\u5e37\u97ec\uff0c\u6bb7\u5c7a\u7537\uff0c\u738b\u8bda\uff0c\u7b49\uff1a\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u4e2d\u7684\u8d28\u5b50\u4f20\u5bfc\u53ca\u5176\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e94\u7528"},"content":{"rendered":"
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\u25cf<\/span> \u5f15\u7528\u672c\u6587\uff1a<\/strong>\u9ad8\u5e37\u97ec, \u6bb7\u5c7a\u7537, \u6d82\u81ea\u5f3a, \u7b49. \u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\u4e2d\u7684\u8d28\u5b50\u4f20\u5bfc\u53ca\u5176\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e94\u7528[J]. \u5316\u5de5\u8fdb\u5c55, 2022, 41(S1): 260-268.<\/span><\/span><\/p>\n<\/section>\n<\/section>\n

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\u25cf<\/span> DOI\uff1a<\/strong>10.16085\/j.issn.1000-6613.2022-1150<\/span><\/span><\/p>\n<\/section>\n<\/section>\n

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\u8d28\u5b50\u4ea4\u6362\u819c\uff08proton exchange membrane\uff0cPEM\uff09\u662f\u4fdd\u8bc1\u71c3\u6599\u7535\u6c60\u5b89\u5168\u3001\u9ad8\u6548\u8fd0\u884c\u7684\u5173\u952e\u90e8\u4ef6\u3002\u5f53\u524d\uff0cNafion\u53ca\u90e8\u5206Nafion\u884d\u751f\u7269PEM\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u71c3\u6599\u7535\u6c60\u3001\u7535\u89e3\u5236\u6c22\u3001\u4f20\u611f\u68c0\u6d4b\u3001\u6db2\u6d41\u7535\u6c60\u7b49\u9886\u57df\u3002\u4f46\u662f\uff0c\u5176\u4ecd\u5b58\u5728\u5236\u9020\u6210\u672c\u8fc7\u9ad8\u3001\u9ad8\u6548\u6e29\u5ea6\u8303\u56f4\u72ed\u7a84\uff08\uff09\u7b49\u95ee\u9898\u3002\u8fd1\u5e74\u6765\uff0c\u90e8\u5206\u91d1\u5c5e\u6709\u673a\u6846\u67b6\u6750\u6599\uff08metal-organic frameworks\uff0cMOFs\uff09\u56e0\u5177\u6709\u7ed3\u6676\u6027\u3001\u53ef\u8bbe\u8ba1\u6027\u548c\u9ad8\u6bd4\u8868\u9762\u79ef\u7b49\u4f18\u70b9\uff0c\u4f5c\u4e3a\u6f5c\u5728\u7684\u65b0\u578b\u8d28\u5b50\u5bfc\u4f53\uff0c\u88ab\u7528\u4e8e\u4fee\u9970\u3001\u6539\u8fdb\u73b0\u6709\u9ad8\u5206\u5b50\u8d28\u5b50\u4ea4\u6362\u819c\uff0c\u6216\u76f4\u63a5\u88ab\u4f5c\u4e3a\u4e3b\u8981\u8d28\u5b50\u4f20\u5bfc\u4ecb\u8d28\u5236\u6210\u8d28\u5b50\u4ea4\u6362\u819c\uff0c\u53d6\u5f97\u4e86\u4e00\u7cfb\u5217\u91cd\u8981\u8fdb\u5c55\u3002\u672c\u6587\u8be6\u7ec6\u4ecb\u7ecd\u4e86\u5728MOFs\u4e2d\u4e94\u79cd\u8d28\u5b50\u4f20\u5bfc\u7684\u5e38\u89c1\u65b9\u5f0f\uff0c\u7efc\u8ff0\u4e86\u8fd1\u5e74\u6765\u56fd\u5185\u5916\u5728\u9ad8\u6027\u80fd\u8d28\u5b50\u4f20\u5bfcMOFs\u9886\u57df\u7684\u4ee3\u8868\u6027\u6210\u679c\uff0c\u603b\u7ed3\u4e86\u8d28\u5b50\u4f20\u5bfcMOFs\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u4e09\u7c7b\u5e38\u89c1\u5e94\u7528\u65b9\u6cd5\uff0c\u6307\u51faMOFs\u6750\u6599\u5728\u63d0\u9ad8PEM\u8d28\u5b50\u7535\u5bfc\u7387\u3001\u964d\u4f4ePEM\u6210\u672c\u3001\u62d3\u5bbdPEM\u9ad8\u6548\u5de5\u4f5c\u533a\u95f4\u7b49\u65b9\u9762\u5177\u6709\u5de8\u5927\u7684\u53d1\u5c55\u6f5c\u529b\u3002\u6700\u540e\uff0c\u672c\u6587\u63d0\u51fa\u73b0\u6709MOFs\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e94\u7528\u8fd8\u5b58\u5728\u7a33\u5b9a\u6027\u3001\u8010\u4e45\u6027\u3001\u6709\u5bb3\u7269\u8d28\u9038\u51fa\u7b49\u65b9\u9762\u7684\u95ee\u9898\uff0c\u8fd9\u4e3a\u65b0\u578bMOFs\u8d28\u5b50\u4ea4\u6362\u819c\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u53c2\u8003\u4e0e\u601d\u8def\u3002<\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\uff08proton exchange membrane fuel cell\uff0cPEMFC\uff09\u4f5c\u4e3a\u4e00\u79cd\u53ef\u5c06\u71c3\u6599\u5316\u5b66\u80fd\u76f4\u63a5\u8f6c\u5316\u4e3a\u7535\u80fd\u7684\u80fd\u91cf\u8f6c\u6362\u88c5\u7f6e\uff0c\u56e0\u5177\u6709\u9ad8\u6548\u3001\u73af\u4fdd\u3001\u9ad8\u80fd\u91cf\u5bc6\u5ea6\u3001\u53cd\u5e94\u6e29\u548c\u3001\u632f\u52a8\u566a\u58f0\u5c0f\u7b49\u4f17\u591a\u4f18\u52bf\uff0c\u53d7\u5230\u4e86\u5e7f\u6cdb\u5173\u6ce8\u3002\u4ee5H2<\/sub>\/O2<\/sub>\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u4e3a\u4f8b\uff0cH2<\/sub>\u5728\u9633\u6781\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\uff0c\u88ab\u6c27\u5316\u4e3a\u8d28\u5b50\uff0c\u5e76\u91ca\u653e\u51fa\u7535\u5b50\u3002\u7535\u5b50\u4ece\u71c3\u6599\u7535\u6c60\u9633\u6781\u7ecf\u7531\u5916\u7535\u8def\u5bf9\u5916\u505a\u529f\u540e\u5230\u8fbe\u9634\u6781\uff0c\u540c\u65f6\u8d28\u5b50\u7a7f\u8fc7\u8d28\u5b50\u4ea4\u6362\u819c\u5230\u8fbe\u9634\u6781\uff0c\u5728\u9634\u6781\u50ac\u5316\u5242\u7684\u4f5c\u7528\u4e0b\uff0c\u8d28\u5b50\u3001\u7535\u5b50\u4e0e\u6c27\u6c14\u4e09\u8005\u53d1\u751f\u53cd\u5e94\uff0c\u751f\u6210H2<\/sub>O\u3002\u7531\u6b64\u53ef\u89c1\uff0c\u8d28\u5b50\u4ea4\u6362\u819c\u4f5c\u4e3aPEMFC\u8fd0\u884c\u8fc7\u7a0b\u4e2d\u4e0d\u53ef\u6216\u7f3a\u7684\u8d28\u5b50\u4f20\u5bfc\u4ecb\u8d28\uff0c\u662f\u4fdd\u8bc1\u71c3\u6599\u7535\u6c60\u5b89\u5168\u3001\u9ad8\u6548\u8fd0\u884c\u7684\u5173\u952e\u90e8\u4ef6\u3002\u6b64\u5916\uff0c\u8d28\u5b50\u4ea4\u6362\u819c\u8fd8\u88ab\u5e7f\u6cdb\u5e94\u7528\u4e8e\u6c2f\u78b1\u5de5\u4e1a\u3001PEM\u7535\u89e3\u5236\u6c22\u3001\u4f20\u611f\u68c0\u6d4b\u3001\u6db2\u6d41\u7535\u6c60\u7b49\u9886\u57df\u3002<\/span><\/p>\n

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MOFs\u4e2d\u5e38\u89c1\u7684\u8d28\u5b50\u4f20\u5bfc\u65b9\u5f0f<\/strong><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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\u4ee5\u6c34\u4f5c\u4e3a\u8d28\u5b50\u5bfc\u7535\u4ecb\u8d28\uff0c\u7814\u7a76\u4eba\u5458\u5df2\u5bf9\u8d28\u5b50\u7684\u5bfc\u7535\u673a\u7406\u8fdb\u884c\u4e86\u5e7f\u6cdb\u7684\u7814\u7a76\u3002\u8003\u8651\u5230\u8d28\u5b50\u7684\u6269\u6563\u8fd0\u52a8\uff0c\u8d28\u5b50\u4f20\u5bfc\u4e3b\u8981\u5305\u62ec\u8df3\u8dc3\u673a\u5236\uff08Grotthus mechanism\uff09\u548c\u8fd0\u8f7d\u673a\u5236\uff08Vehicle mechanism\uff09\u4e24\u79cd\u673a\u5236\u3002\u4ee5\u6c34\u5a92\u4ecb\u8d28\u5b50\u4f20\u5bfc\u4e3a\u4f8b\uff0c\u5728\u8df3\u8dc3\u673a\u5236\u4e0b\uff0c\u8d28\u5b50\u4e0e H2<\/sub>O\u5f62\u6210\u5404\u79cd\u6c34\u5408\u79bb\u5b50 H+<\/sup>(H2<\/sub>O)n<\/em><\/sub>\uff0c\u6c34\u5408\u79bb\u5b50\u4e0e\u90bb\u8fd1\u5206\u5b50\u6216\u57fa\u56e2\u5f62\u6210\u8fde\u7eed\u7684\u6c22\u952e\u7f51\u7edc\uff0c\u8d28\u5b50\u6cbf\u7740\u6c27\u952e\u7f51\u7edc\u4ece\u4e00\u4e2a\u6c34\u5408\u79bb\u5b50\u4e0a\u8df3\u8dc3\u5230\u90bb\u8fd1\u7684\u4e0b\u4e00\u4e2a\u8d28\u5b50\u8df3\u8dc3\u4f4d\u70b9\uff0c\u4ece\u800c\u5f62\u6210\u4e00\u4e2a\u5b8c\u6574\u7684\u8d28\u5b50\u4f20\u5bfc\u8def\u5f84\uff1b\u800c\u5728\u8fd0\u8f7d\u673a\u5236\u4e0b\uff0c\u6c34\u5408\u79bb\u5b50\u5728\u4eb2\u6c34\u901a\u9053\u4e2d\u6cbf\u7740\u4e00\u5b9a\u7684\u65b9\u5411\u6269\u6563\u8fd0\u52a8\uff0c\u540c\u65f6\u672a\u88ab\u8d28\u5b50\u5316\u7684\u6c34\u5206\u5b50\u5219\u6cbf\u76f8\u53cd\u65b9\u5411\u8fd0\u52a8\uff0c\u7531\u6b64\u5b9e\u73b0\u8d28\u5b50\u7684\u4f20\u5bfc\u3002\u4e24\u79cd\u673a\u5236\u5747\u5b58\u5728\u660e\u786e\u7684\u6d3b\u5316\u80fd\uff08E<\/em>a<\/sub>\uff09\u8303\u56f4\uff0c\u901a\u8fc7\u5c06\u968f\u6e29\u5ea6\u53d8\u5316\u7684\u7535\u5bfc\u7387\u4e0e\u963f\u4f26\u5c3c\u4e4c\u65af\u65b9\u7a0b\uff08Arrhenius equation\uff09\u62df\u5408\u53ef\u5f97\u5230\u4e0d\u540c\u4f20\u5bfc\u673a\u5236\u4e0b\u7684E<\/em>a<\/sub>\u3002\u5176\u4e2d\uff0c\u56e0\u8df3\u8dc3\u673a\u5236\u4e0b\u4ec5\u8d28\u5b50\u81ea\u8eab\u53d1\u751f\u4e86\u79fb\u52a8\uff0c\u6545\u5176\u6240\u9700\u6d3b\u5316\u80fd\u76f8\u5bf9\u8f83\u4f4e\uff08E<\/em>a<\/sub><0.4eV\uff09\uff1b\u76f8\u53cd\uff0c\u5728\u8fd0\u8f7d\u673a\u5236\u4e0b\u7684\u6d3b\u5316\u80fd\u5219\u76f8\u5bf9\u8f83\u9ad8\uff08E<\/em>a<\/sub>>0.4eV\uff09\u3002\u7531\u6b64\uff0c\u6d3b\u5316\u80fd\u53ef\u4f5c\u4e3a\u4e00\u4e2a\u76f4\u89c2\u7684\u5224\u636e\uff0c\u6765\u63a8\u65ad\u8d28\u5b50\u4f20\u5bfc\u673a\u5236\u3002\u66f4\u8fdb\u4e00\u6b65\uff0c\u5728\u90e8\u5206\u8d28\u5b50\u4f20\u5bfc\u6750\u6599\u4e2d\u5b58\u5728\u4e24\u79cd\u673a\u5236\u534f\u540c\u4f5c\u7528\u7684\u60c5\u51b5\uff0c\u56e0\u6b64\u7cbe\u786e\u7684\u4f20\u5bfc\u673a\u5236\u5e94\u7efc\u5408\u7ed3\u6784\u5206\u6790\u3001\u7535\u5bfc\u7387\u6d4b\u8bd5\u548c\u5149\u8c31\u5b66\u6d4b\u91cf\uff08\u4f8b\u5982\u51c6\u5f39\u6027\u4e2d\u5b50\u80fd\u8c31\u548c\u56fa\u4f53\u6838\u78c1\u5171\u632f\u6ce2\u8c31\u7b49\uff09\u7ed3\u679c\u6765\u5224\u5b9a\u3002<\/p>\n

\u7136\u800c\uff0c\u5728\u5b9e\u9645MOFs\u7684\u5b54\u9053\u4e2d\uff0c\u8d28\u5b50\u6240\u5904\u5fae\u73af\u5883\u53ef\u80fd\u975e\u5e38\u590d\u6742\u3002\u9488\u5bf9MOFs\u4e2d\u7684\u8d28\u5b50\u4f20\u5bfc\uff0cKitagawa\u8bfe\u9898\u7ec4\u5c06\u5176\u7b80\u5316\u3001\u5f52\u7eb3\u4e3a\u4e94\u79cd\u7c7b\u578b\u7684\u5e38\u89c1\u4f20\u5bfc\u65b9\u5f0f\uff0c\u89c1\u56fe1\u3002\u5728MOFs\u6750\u6599\u4e2d\uff0c\u8d28\u5b50\u7684\u4f20\u5bfc\u9014\u5f84\u53ef\u4e3a\u51e0\u79cd\u7c7b\u578b\u7684\u4f20\u5bfc\u65b9\u5f0f\u7684\u7ec4\u5408\uff0c\u4e14\u53ef\u80fd\u5b58\u5728\u4e0d\u540c\u7c7b\u578b\u4e4b\u95f4\u7684\u534f\u540c\u6548\u5e94\u3002\u672c\u8282\u63a5\u4e0b\u6765\u5c06\u5bf9\u5404\u5e38\u89c1\u4f20\u5bfc\u65b9\u5f0f\u8fdb\u884c\u7b80\u4ecb\u3002<\/p>\n<\/section>\n

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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n
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<\/section>\n<\/section>\n<\/section>\n
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\u56fe1\u00a0\u00a0<\/strong>MOFs\u4e2d\u4e94\u79cd\u5e38\u89c1\u7684\u8d28\u5b50\u4f20\u5bfc\u65b9\u5f0f<\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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1.1<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u4f20\u5bfc\u65b9\u5f0f\u4e00: \u501f\u52a9\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\u8fdb\u884c\u8d28\u5b50\u4f20\u5bfc<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u8d28\u5b50\u4f20\u5bfc\u8f7d\u4f53\u6d53\u5ea6\u4e0e\u8d28\u5b50\u7535\u5bfc\u7387\u76f4\u63a5\u76f8\u5173\u3002\u5f53\u501f\u52a9\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\uff08\u4f8b\u5982\u9178\u5206\u5b50\u3001\u8d28\u5b50\u6027\u6709\u673a\u5206\u5b50\u3001\u6742\u591a\u9178\u3001\u91d1\u5c5e-\u6709\u673a\u591a\u9762\u4f53\u7b49\uff09\u8fdb\u884c\u8d28\u5b50\u4f20\u5bfc\u65f6\uff0c\u53ef\u6700\u76f4\u63a5\u7684\u5229\u7528MOFs\u9ad8\u5b54\u9699\u7387\u7684\u4f18\u52bf\uff0c\u4ee5\u5927\u91cf\u5438\u9644\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\u5b9e\u73b0\u8f83\u9ad8\u7684\u8f7d\u4f53\u6d53\u5ea6\u3002\u4f8b\u5982\uff0cLee\u7b49\u5c06\u542b\u6709\u78fa\u9178\u57fa\u7684\u529f\u80fd\u5316\u94dc\u57fa\u91d1\u5c5e-\u6709\u673a\u591a\u9762\u4f53\uff08metal-organic polyhedral\uff0cMOP\uff09\u5f15\u5165\u4ecb\u5b54MOF\uff08PCN-777\uff09\u4e2d\uff0c\u5982\u56fe2\u3002\u5176\u7535\u5bfc\u7387\u5728\u4e0d\u540c\u6761\u4ef6\u4e0b\u76f8\u5bf9\u7eafPCN-777\u63d0\u9ad8\u4e86\u7ea61~3\u4e2a\u6570\u91cf\u7ea7\uff0c\u4e14\u6d3b\u5316\u80fd\u75310.87eV\u964d\u4f4e\u81f30.66eV\uff1bPhang\u7b49\u5c06\u542b\u6709\u516d\u8fb9\u5f62\u901a\u9053\u7684Ni-MOF-74\u6d78\u6ce1\u4e8e\u4e0d\u540cpH\u7684\u786b\u9178\u6eb6\u6db2\u4e2d\uff0c\u53d1\u73b0\u5f53\u786b\u9178\u6eb6\u6db2\u7684pH\u4e3a1.8\u65f6\uff0c\u6d78\u6ce1\u540e\u7684Ni-MOF-74\u5c55\u73b0\u51fa\u6700\u9ad8\u7684\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u5176\u572880\u2103\uff0c95%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u53ef\u8fbe2.2\u00d710-2<\/sup>S\/cm\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5f53\u88c5\u8f7d\u8fc7\u591a\u7684\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\u540e\uff0cMOFs\u53ef\u80fd\u51fa\u73b0\u7ed3\u6784\u7a33\u5b9a\u6027\u95ee\u9898\u3002\u56e0\u6b64\u8981\u60f3\u501f\u52a9\u529f\u80fd\u5ba2\u4f53\u5206\u5b50\u5b9e\u73b0\u9ad8\u6548\u8d28\u5b50\u4f20\u5bfc\uff0cMOFs\u7ed3\u6784\u5fc5\u987b\u6709\u975e\u51e1\u7684\u7a33\u5b9a\u6027\u3002<\/p>\n

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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n
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<\/section>\n<\/section>\n<\/section>\n
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\u56fe2\u00a0\u00a0<\/strong>MOPMOF\u590d\u5408\u8d28\u5b50\u5bfc\u4f53\u793a\u610f\u56fe<\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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1.2<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u4f20\u5bfc\u65b9\u5f0f\u4e8c\uff1a\u501f\u52a9\u53cd\u79bb\u5b50\u8fdb\u884c\u8d28\u5b50\u4f20\u5bfc<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u5728MOFs\u5408\u6210\u8fc7\u7a0b\u4e2d\uff0c\u53ef\u80fd\u540c\u65f6\u5f62\u6210\u5e26\u7535\u6846\u67b6\u4e0e\u53cd\u79bb\u5b50\uff08\u4f8b\u5982H3<\/sub>O+<\/sup>\u3001\"\u6e05\u534e\u5927\u5b66\u3001\"\u6e05\u534e\u5927\u5b66\u7b49\uff09\u3002\u8fd9\u4e9b\u53cd\u79bb\u5b50\u53ef\u4e0e\u5ba2\u4f53\u6c34\u6216\u6846\u67b6\u5f62\u6210\u6c22\u952e\uff0c\u8fdb\u800c\u5f62\u6210\u53ef\u5b9e\u73b0\u9ad8\u6548\u8d28\u5b50\u4f20\u5bfc\u7684\u8fde\u7eed\u6c22\u952e\u7f51\u7edc\u3002Wei\u7b49\u62a5\u9053\u4e86\u4e00\u79cd\u65b0\u578b\u8d28\u5b50\u5bfc\u7535MOF [(Me2<\/sub>NH2<\/sub>) [Eu(L)]\uff0cL=5-\u4e9a\u7532\u57fa\u81a6\u9178\u95f4\u82ef\u4e8c\u7532\u9178]\u7684\u6eb6\u5242\u70ed\u5408\u6210\u65b9\u6cd5\uff0c\u56e0\u5c42\u72b6\u6846\u67b6[Eu(L)]-<\/sup>\u5e26\u8d1f\u7535\uff0c\u6545\u7ed3\u6784\u4e2d\u5b58\u5728\u63d2\u5c42\u7684 (Me2<\/sub>NH2<\/sub>)+<\/sup> \u53cd\u79bb\u5b50\u3002\u53cd\u79bb\u5b50\u4e0e\u76f8\u90bb\u7684\u672a\u914d\u4f4d\u81a6\u9178\u57fa\u56e2\u4e2d\u7684O\u539f\u5b50\u76f8\u4e92\u4f5c\u7528\uff0c\u5f62\u6210\u4e86\u5e73\u884c\u4e8ec\u8f74\u7684\u5f3a\uff08N\u2014H\u00b7\u00b7\u00b7O\uff09\u6c22\u952e\u94fe\u3002\u8d28\u5b50\u6cbf\u4e0a\u8ff0\u6c22\u952e\u94fe\u4ee5\u8df3\u8dc3\u673a\u5236\u4f20\u5bfc\uff08E<\/em>a<\/sub>=0.21eV\uff09\uff0c\u5728150\u2103\u4e0b\u5b9e\u73b0\u4e861.25\u00d710-3<\/sup>S\/cm\u7684\u65e0\u6c34\u8d28\u5b50\u7535\u5bfc\u7387\u3002Yaghi\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u7cfb\u5217\u4e09\u7ef4\u91d1\u5c5e-\u513f\u8336\u915a\u6846\u67b6\u7ed3\u6784\uff0c\u5176\u4e2dFe-CAT-5\u7684\u5355\u6676X\u5c04\u7ebf\u884d\u5c04\u7ed3\u6784\u663e\u793a\u7ed3\u5408\u4e86\u786b\u9178\u76d0\u914d\u4f53\u7684DMA\uff08dimethylammonium\uff09\u4f5c\u4e3a\u53cd\u79bb\u5b50\u5b58\u5728\u4e8e\u6846\u67b6\u7684\u5b54\u5185\uff0c\u4f7f\u5f97\u8be5MOF\u6210\u4e3a\u7406\u60f3\u7684\u8d28\u5b50\u5bfc\u4f53\uff0c\u572825\u2103\uff0c98%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u9ad8\u8fbe5.0\u00d710-2<\/sup>S\/cm\u3002\u7c7b\u4f3c\u7684\uff0cNagarkar\u7b49\u5229\u7528[(Me2<\/sub>NH2<\/sub>)6<\/sub>SO4<\/sub>]4+<\/sup>\u5f62\u6210\u7684\u6c22\u952e\u7f51\u7edc\uff0c\u5728MOF\u4e2d\u540c\u65f6\u5b9e\u73b0\u4e86\u6709\u6c34\u3001\u65e0\u6c34\u73af\u5883\u4e0b\u7684\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u5176\u4e2d\u5728\u6709\u6c34\u73af\u5883\u4e0b\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u53ef\u4e0eNafion\u76f8\u5f53\uff0c\u975e\u5e38\u9002\u5408\u4e8e\u5728\u71c3\u6599\u7535\u6c60\u4e2d\u5e94\u7528\u3002<\/p>\n

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1.3<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u4f20\u5bfc\u65b9\u5f0f\u4e09\uff1a\u501f\u52a9\u6709\u673a\u914d\u4f53\u4e2d\u7684\u975e\u914d\u4f4d\u5b98\u80fd\u56e2\u8fdb\u884c\u8d28\u5b50\u4f20\u5bfc<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

MOFs\u7684\u6709\u673a\u914d\u4f53\u4e2d\u7684\u90e8\u5206\u975e\u914d\u4f4d\u5b98\u80fd\u56e2\uff08\u4f8b\u5982\u2014OH\u3001\u2014NH2<\/sub>\u3001\u2014COOH\u3001\u2014SO3<\/sub>H\u3001\u2014PO3<\/sub>H2<\/sub>\u7b49\uff09\u6709\u52a9\u4e8e\u5b9e\u73b0\u9ad8\u6548\u8d28\u5b50\u4f20\u5bfc\u3002\u8fd9\u4e9b\u975e\u914d\u4f4d\u5b98\u80fd\u56e2\u65e2\u53ef\u901a\u8fc7\u4f7f\u7528\u9884\u5148\u8bbe\u8ba1\u7684\u6709\u673a\u914d\u4f53\u5f15\u5165\uff0c\u4e5f\u53ef\u901a\u8fc7\u5bf9\u5408\u6210\u597d\u7684MOFs\u8fdb\u884c\u540e\u5904\u7406\u6765\u5f15\u5165\u3002Kitagawa\u8bfe\u9898\u7ec4\u9488\u5bf9MIL-53\u7cfb\u5217MOFs\uff0c\u9996\u6b21\u5728\u540c\u7ed3\u6784\u7cfb\u5217\u4e2d\uff0c\u901a\u8fc7\u6539\u53d8\u914d\u4f53\u4e0a\u975e\u914d\u4f4d\u7684\u5b98\u80fd\u56e2\u7c7b\u578b\uff0c\u5b9e\u73b0\u4e86\u5728\u8f83\u5bbd\u8303\u56f4\u5185\u63a7\u5236MOFs\u7684\u8d28\u5b50\u5bfc\u7535\u6027\uff0c\u89c1\u56fe3\u3002Rought\u7b49\u8bbe\u8ba1\u4e86\u4e09\u79cd\u591a\u7fa7\u9178\u529f\u80fd\u5316\u914d\u4f53\u5e76\u7531\u6b64\u5236\u5907\u4e86\u4e09\u79cd\u65b0\u578b\u9ad8\u7a33\u5b9a\u6027\u94a1\u57faMOFs\uff08MFM-510\u3001MFM-511\u3001MFM-512\uff09\u3002\u4e0eMFM-510\u548cMFM-511\u76f8\u6bd4\uff0cMFM-512\u56e0\u4e3a\u6709\u7fa7\u9178\u57fa\u56e2\u76f4\u63a5\u5782\u5165\u6846\u67b6\u7684\u5b54\u9053\uff0c\u6545\u5728\u76f8\u540c\u6761\u4ef6\u4e0b\u8d28\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u4e862\u4e2a\u6570\u91cf\u7ea7\uff0c\u8fd9\u8bc1\u5b9e\u4e86\u5728MOFs\u5b54\u5185\u52a0\u5165\u201c\u81ea\u7531\u201d\u7fa7\u9178\u57fa\u56e2\u662f\u4e00\u79cd\u63d0\u9ad8\u8d28\u5b50\u5bfc\u7535\u6027\u7684\u6709\u6548\u7b56\u7565\u3002\u5317\u4eac\u5de5\u4e1a\u5927\u5b66\u7684Yang\u7b49\u62a5\u9053\u4e86\u4e00\u79cdCr(\u2162)\u57fa\u67d4\u6027MOF[BUT-8(Cr)A]\u3002\u8be5\u4e09\u7ef4\u6846\u67b6\u6750\u6599\u5177\u6709\u4e00\u7ef4\u5b54\u9053\uff0c\u9ad8\u5bc6\u5ea6\u7684\u2014SO3<\/sub>H\u4f4d\u70b9\u6392\u5217\u5728\u5b54\u9053\u8868\u9762\u7528\u4e8e\u8d28\u5b50\u4f20\u5bfc\u3002\u67d4\u6027\u6846\u67b6\u7ed3\u6784\u5728\u4e0d\u540c\u7684\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u53ef\u81ea\u9002\u5e94\u8c03\u6574\uff0c\u5b9e\u73b0\u6c34\u5206\u5b50\u4ecb\u5bfc\u7684\u8d28\u5b50\u4f20\u5bfc\u901a\u8def\u7684\u7545\u901a\u3002\u7531\u6b64\uff0cBUT-8(Cr)A\u4e0d\u4ec5\u572880\u2103\uff0c100%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e860.127S\/cm\u7684\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u800c\u4e14\u5728\u8f83\u5bbd\u7684\u6e7f\u5ea6\u548c\u6e29\u5ea6\u8303\u56f4\u5185\u4fdd\u6301\u4e86\u8f83\u9ad8\u7684\u8d28\u5b50\u5bfc\u7535\u6027\u3002<\/p>\n

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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n
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\n
\n
\n
\n
<\/section>\n<\/section>\n<\/section>\n
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\u56fe3\u00a0\u00a0<\/strong>MIL-53\u7cfb\u5217MOFs\u4e2d\u5b98\u80fd\u56e2\u7c7b\u578b\u4e0e\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u5173\u7cfb<\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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1.4<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u4f20\u5bfc\u65b9\u5f0f\u56db\uff1a\u501f\u52a9\u4e0e\u91d1\u5c5e\u4e2d\u5fc3\u914d\u4f4d\u7684\u529f\u80fd\u5206\u5b50\u8fdb\u884c\u8d28\u5b50\u4f20\u5bfc<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u5bf9\u4e8e\u91d1\u5c5e\u4e2d\u5fc3\u914d\u4f4d\u4e0d\u9971\u548c\u7684MOFs\uff0c\u90e8\u5206\u53ef\u4e0e\u91d1\u5c5e\u4e2d\u5fc3\u914d\u4f4d\u7684\u529f\u80fd\u5206\u5b50\uff08\u4f8b\u5982H2<\/sub>O\u3001\u4e59\u9187\u5206\u5b50\u3001\u54aa\u5511\u5206\u5b50\u7b49\uff09\u6709\u52a9\u4e8e\u5b9e\u73b0\u9ad8\u6548\u8d28\u5b50\u4f20\u5bfc\u3002\u4f8b\u5982\uff0cHupp\u8bfe\u9898\u7ec4\u5c55\u793a\u4e86\u4e00\u4e2a\u901a\u8fc7\u914d\u4f4d\u5316\u5b66\u65b9\u6cd5\u8c03\u63a7MOFs\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u5b9e\u4f8b\u3002\u5176\u5229\u7528HKUST-1\u578bMOF\u4e2d\u914d\u4f4d\u4e0d\u9971\u548c\u7684Cu(\u2161)\u6868\u8f6e\u5f62\u91d1\u5c5e\u4e2d\u5fc3\uff0c\u5206\u522b\u4ee4\u6c34\u5206\u5b50\u3001\u4e59\u9187\u5206\u5b50\u548c\u4e59\u8148\u5206\u5b50\u5360\u636e\u7a7a\u914d\u4f4d\u70b9\uff0c\u6b64\u540e\u518d\u66b4\u9732\u4e8e\u7532\u9187\u84b8\u6c7d\u4e2d\u5438\u9644\u7532\u9187\u3002\u7ed3\u679c\u8868\u660e\uff0c\u4e0e\u4e59\u8148\u5206\u5b50\u5360\u636e\u7a7a\u914d\u4f4d\u70b9\u7684\u60c5\u51b5\u76f8\u6bd4\uff0c\u5f53Cu(\u2161)\u91d1\u5c5e\u4e2d\u5fc3\u7684\u7a7a\u914d\u4f4d\u70b9\u88ab\u6c34\u5206\u5b50\u5360\u636e\u65f6\uff0c\u5176\u8d28\u5b50\u7535\u5bfc\u7387\u53ef\u63d0\u534775\u500d\u3002\u8fd9\u662f\u56e0\u4e3a\u867d\u7136HKUST-1\u662f\u4e2d\u6027\u7684\uff0c\u4f46\u914d\u4f4d\u540e\u7684\u6c34\u5206\u5b50\u5177\u6709\u8db3\u591f\u7684\u9178\u6027\uff0c\u4f7f\u5176\u53ef\u5411\u7532\u9187\u5206\u5b50\u63d0\u4f9b\u8d28\u5b50\uff0c\u7531\u6b64\u663e\u8457\u63d0\u5347\u4e86\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u5468\u5b8f\u624d\u8bfe\u9898\u7ec4\u4ee5\u540c\u4e00\u79cd\u94c1\u57faMOF\u4f5c\u4e3a\u7a7a\u767d\u5bf9\u7167\u7ec4\uff0c\u5206\u522b\u7814\u7a76\u4e86\u7269\u7406\u5438\u9644\u54aa\u5511\u5206\u5b50\uff08Im@Fe-MOF\uff09\u548c\u54aa\u5511\u5206\u5b50\u5360\u636e\u94c1\u5468\u56f4\u7a7a\u914d\u4f4d\u70b9\uff08Im-Fe-MOF\uff09\u4e24\u79cd\u60c5\u51b5\u4e0b\uff0c\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u4e0d\u540c\uff0c\u89c1\u56fe4\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5728\u5ba4\u6e29\u6761\u4ef6\u4e0b\uff0cIm-Fe-MOF\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u6bd4Fe-MOF\u548cIm@Fe-MOF\u9ad8\u51fa\u7ea6\u4e24\u4e2a\u6570\u91cf\u7ea7\uff0c\u5176\u572860\u2103\uff0c98%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e861.21\u00d710-2<\/sup>S\/cm\u7684\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u8fd9\u662f\u56e0\u4e3a\u4e0eFe-MOF\uff08\u5728\u6f6e\u6e7f\u73af\u5883\u4e0b\uff0c\u6c34\u5206\u5b50\u5360\u636e\u7a7a\u914d\u4f4d\u70b9\uff09\u76f8\u6bd4\uff0cIm-Fe-MOF\u4e2d\u914d\u4f4d\u7684\u54aa\u5511\u5206\u5b50\u4e3a\u8d28\u5b50\u4f20\u5bfc\u63d0\u4f9b\u4e86\u66f4\u5927\u7684\u8d28\u5b50\u6d53\u5ea6\uff1b\u4e0eIm@Fe-MOF\u5b54\u9699\u4e2d\u65e0\u5e8f\u6392\u5217\u7684\u7269\u7406\u5438\u9644\u7684\u54aa\u5511\u5206\u5b50\u76f8\u6bd4\uff0cIm-Fe-MOF\u4e2d\u901a\u8fc7\u914d\u4f4d\u952e\u56fa\u5b9a\u7684\u54aa\u5511\u5206\u5b50\u66f4\u5bb9\u6613\u5f62\u6210\u8d28\u5b50\u4f20\u5bfc\u901a\u8def\u3002<\/p>\n

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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n
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<\/section>\n<\/section>\n<\/section>\n
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\u56fe4\u00a0\u00a0<\/strong>\u54aa\u5511\u5206\u5b50\u5bf9MOFs\u8d28\u5b50\u7535\u5bfc\u7387\u7684\u5f71\u54cd<\/p>\n<\/section>\n<\/section>\n

\n
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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0c\u5f53\u56fa\u5b9a\u529f\u80fd\u5206\u5b50\u7684\u914d\u4f4d\u952e\u8fc7\u5f3a\u65f6\uff0c\u53c8\u53ef\u80fd\u963b\u788d\u8d28\u5b50\u7684\u9ad8\u6548\u4f20\u5bfc\u3002Bureekaew\u7b49\u62a5\u9053\u4e86\u4e24\u79cd\u88c5\u8f7d\u54aa\u5511\u5206\u5b50\u5b9e\u73b0\u8d28\u5b50\u4f20\u5bfc\u7684MOFs\u3002\u6709\u8da3\u7684\u662f\uff0c\u4e24\u79cdMOFs\u4e2d\u76f8\u5bf9\u88c5\u8f7d\u66f4\u5c11\u54aa\u5511\u5206\u5b50\u7684MOF\u5c55\u73b0\u51fa\u663e\u8457\u66f4\u9ad8\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u8fd9\u662f\u56e0\u4e3a\uff0c\u53e6\u4e00\u79cdMOF\u867d\u53ef\u88c5\u8f7d\u66f4\u591a\u7684\u8d28\u5b50\u4f20\u5bfc\u8f7d\u4f53\uff0c\u4f46\u5927\u91cf\u8f7d\u4f53\u4e0e\u6846\u67b6\u4e4b\u95f4\u5b58\u5728\u8fc7\u5f3a\u7684\u76f8\u4e92\u4f5c\u7528\uff0c\u8d28\u5b50\u5728\u8fd9\u4e9b\u88ab\u201c\u56fa\u5b9a\u201d\u4f4f\u7684\u54aa\u5511\u5206\u5b50\u95f4\u4f20\u5bfc\u65f6\u9700\u8981\u514b\u670d\u8f83\u5927\u7684\u6d3b\u5316\u80fd\u3002<\/p>\n

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1.5<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u4f20\u5bfc\u65b9\u5f0f\u4e94: \u501f\u52a9MOFs\u4e2d\u7684\u7f3a\u9677\u6765\u4fc3\u8fdb\u8d28\u5b50\u4f20\u5bfc<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u90e8\u5206MOFs\u4e2d\u7684\u7f3a\u9677\u4f4d\u70b9\u53ef\u901a\u8fc7\u521b\u9020\u989d\u5916\u7684\u4f20\u5bfc\u9014\u5f84\u6765\u4fc3\u8fdb\u8d28\u5b50\u4f20\u5bfc\u3002\u4f8b\u5982\uff0cKitagawa\u8bfe\u9898\u7ec4\u62a5\u9053\u4e86\u4e00\u79cd\u72ec\u7279\u7684\u9506\u57faMOF\uff0c\u8be5MOF\u4e2d\u542b\u6709\u5927\u91cf\u7684\u78fa\u9178\u57fa\uff0c\u4fdd\u8bc1\u4e86\u5b54\u9053\u4e2d\u8f83\u9ad8\u7684\u8d28\u5b50\u6d53\u5ea6\u3002\u540c\u65f6\uff0c\u9506\u91d1\u5c5e\u56e2\u7c07\u7684\u7f3a\u9677\u53ef\u6210\u4e3a\u6709\u6548\u7684\u8d28\u5b50\u6355\u83b7\u4f4d\u70b9\u3002\u4f5c\u8005\u5728MOF\u5408\u6210\u8fc7\u7a0b\u4e2d\u52a0\u5165\u4e86\u5f3a\u9178\u4f7f\u7f3a\u9677\u4f4d\u70b9\u7684\u8d28\u5b50\u6355\u83b7\u6027\u8d28\u9971\u548c\uff0c\u5f15\u8d77\u78fa\u9178\u57fa\u7684\u90e8\u5206\u8d28\u5b50\u5316\uff0c\u964d\u4f4e\u4e86MOF\u7684pK<\/em>a<\/sub>\uff0c\u5e76\u7531\u6b64\u5c06\u8d28\u5b50\u7535\u5bfc\u7387\u63d0\u5347\u4e865\u500d\u3002\u6b64\u5916\uff0c\u8be5\u8bfe\u9898\u7ec4\u8fd8\u901a\u8fc7\u8c03\u6574\u91d1\u5c5e\u4e0e\u914d\u4f53\u7684\u6bd4\u4f8b\u3001\u52a0\u5165\u918b\u9178\u548c\u4e0d\u540c\u6d53\u5ea6\u7684\u786c\u8102\u9178\u7b49\u65b9\u5f0f\uff0c\u5236\u5907\u4e86\u4e00\u7cfb\u5217\u5177\u6709\u4e0d\u540c\u7f3a\u9677\u7684UiO-66\u578bMOFs\u3002\u4e00\u65b9\u9762\uff0c\u7f3a\u9677\u5f62\u6210\u7684\u8def\u6613\u65af\u9178\u4f4d\u70b9\u63d0\u4f9b\u4e86\u4e0e\u914d\u4f4d\u6c34\u76f8\u7ed3\u5408\u540e\u53ef\u79fb\u52a8\u8d28\u5b50\uff1b\u53e6\u4e00\u65b9\u9762\uff0c\u7f3a\u9677\u5f15\u53d1\u7684\u5b54\u9053\u4f53\u79ef\u589e\u52a0\uff0c\u589e\u5927\u4e86\u8d28\u5b50\u8fc1\u79fb\u7387\u8fdb\u800c\u63d0\u9ad8\u4e86\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u5728\u4e0a\u8ff0\u4e24\u4e2a\u539f\u56e0\u5171\u540c\u4f5c\u7528\u4e0b\uff0c\u4f5c\u8005\u901a\u8fc7\u5728UiO-66\u4e2d\u63a7\u5236\u7f3a\u9677\u751f\u6210\uff0c\u5c06\u8d28\u5b50\u7535\u5bfc\u7387\u63d0\u9ad8\u4e86\u8fd13\u4e2a\u6570\u91cf\u7ea7\uff0c\u89c1\u56fe5\u3002<\/p>\n

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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n
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<\/section>\n<\/section>\n<\/section>\n
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\u56fe5\u00a0\u00a0<\/strong>UiO-66\u7f3a\u9677\u793a\u610f\u56fe<\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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1.6<\/strong><\/p>\n<\/section>\n<\/section>\n

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\u5c0f\u7ed3<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u4e3a\u66f4\u597d\u5730\u603b\u7ed3\u4e0a\u8ff0MOFs\u4e2d\u5e38\u89c1\u7684\u4e94\u79cd\u8d28\u5b50\u4f20\u5bfc\u65b9\u5f0f\u7684\u7279\u70b9\uff0c\u88681\u4e2d\u5217\u4e3e\u4e86\u5404\u5e38\u89c1\u4f20\u5bfc\u65b9\u5f0f\u7684\u4f18\u52bf\u53ca\u5178\u578b\u4f8b\u5b50\u3002<\/p>\n

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\u88681\u00a0\u00a0<\/strong>MOFs\u4e2d\u4e0d\u540c\u8d28\u5b50\u4f20\u5bfc\u65b9\u5f0f\u7684\u4f18\u52bf\u53ca\u4e3e\u4f8b<\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n
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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n

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2<\/strong><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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MOFs\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e94\u7528<\/strong><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\n

MOFs\u4e3a\u4e0b\u4e00\u4ee3\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\u3001\u5bbd\u6e29\u57df\u8d28\u5b50\u4ea4\u6362\u819c\u7684\u5f00\u53d1\u63d0\u4f9b\u4e86\u4e00\u6761\u6f5c\u5728\u8def\u5f84\u3002\u4f8b\u5982\uff0cLi\u7b49\u5c06\u4e0d\u6325\u53d1\u7684\u5f3a\u9178H2<\/sub>SO4<\/sub>\u5c01\u88c5\u5728\u529f\u80fd\u5316\u7684MIL-101-SO3<\/sub>H\u7684\u5b54\u9699\u4e2d\uff0c\u572870\u2103\u300190%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e861.82S\/cm\u7684\u8d85\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\uff1b\u5373\u4f7f\u662f\u5728-40\u2103\u7684\u4f4e\u6e29\u6761\u4ef6\u4e0b\uff0c\u5176\u8d28\u5b50\u7535\u5bfc\u7387\u4f9d\u65e7\u9ad8\u8fbe0.92\u00d710-2<\/sup>S\/cm\u3002\u73b0\u6709\u8d28\u5b50\u4f20\u5bfcMOFs\u53ef\u5206\u4e3a\u6c34\u5a92\u4ecb\u8d28\u5b50\u4f20\u5bfc\u548c\u65e0\u6c34\u8d28\u5b50\u4f20\u5bfc\u4e24\u7c7b\uff0c\u5176\u4e2d\u6c34\u5a92\u4ecb\u8d28\u5b50\u4f20\u5bfcMOFs\u7684\u9ad8\u6548\u5de5\u4f5c\u6e29\u5ea6\u533a\u95f4\u4e0eNafion\u7c7b\u4f3c\uff0c\u6709\u671b\u5b9e\u73b0\u5bf9Nafion\u53caNafion\u884d\u751f\u7269\u8d28\u5b50\u4ea4\u6362\u819c\u7684\u66ff\u4ee3\uff1b\u800c\u65e0\u6c34\u8d28\u5b50\u4f20\u5bfcMOFs\u7684\u5de5\u4f5c\u6e29\u5ea6\u53ef\u4ee5\u9ad8\u4e8e100\u2103\uff0c\u987a\u5e94PEMFC\u9ad8\u6e29\u5316\u53d1\u5c55\u8d8b\u52bf\uff0c\u6709\u671b\u540c\u65f6\u89e3\u51b3\u8d28\u5b50\u4ea4\u6362\u819c\u71c3\u6599\u7535\u6c60\u5728\u6c34\u7ba1\u7406\u3001\u4f4e\u6e29\u96f6\u4e0b\u542f\u52a8\u7b49\u65b9\u9762\u7684\u96be\u9898\u3002<\/p>\n

\u7136\u800c\uff0cMOFs\u6750\u6599\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e94\u7528\u4f9d\u7136\u9762\u4e34\u8f83\u591a\u56f0\u96be\u3002\u901a\u8fc7\u51b7\u538b\u538b\u7247\u7b49\u5236\u819c\u65b9\u5f0f\uff0c\u53ef\u5c06\u7c89\u672b\u72b6\u7684\u8d28\u5b50\u4f20\u5bfcMOFs\u76f4\u63a5\u5236\u6210MOFs\u57fa\u8d28\u5b50\u4ea4\u6362\u819c\u3002\u7136\u800c\uff0c\u901a\u8fc7\u8fd9\u7c7b\u65b9\u5f0f\u5236\u5907\u7684\u8d28\u5b50\u4ea4\u6362\u819c\u5f80\u5f80\u5b58\u5728\u7a33\u5b9a\u6027\u3001\u8010\u4e45\u6027\u3001\u673a\u68b0\u5f3a\u5ea6\u3001\u6c14\u4f53\u7a9c\u6f0f\u7b49\u65b9\u9762\u7684\u95ee\u9898\uff0c\u96be\u4ee5\u6ee1\u8db3PEMFC\u6216\u5176\u4ed6\u5b9e\u9645\u88c5\u7f6e\u7684\u5e94\u7528\u9700\u6c42\u3002\u672c\u6587\u5c06\u73b0\u6709\u7684MOFs\u6750\u6599\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e38\u89c1\u5e94\u7528\u65b9\u5f0f\u5206\u4e3a\u4e86\u4e09\u7c7b\uff0c\u89c1\u88682\uff0c\u5c06\u5728\u672c\u8282\u4e2d\u5206\u522b\u8fdb\u884c\u7b80\u4ecb\u3002<\/p>\n<\/section>\n

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\n

\u88682\u00a0\u00a0<\/strong>MOFs\u5728\u8d28\u5b50\u4ea4\u6362\u819c\u4e2d\u7684\u5e38\u89c1\u5e94\u7528\u65b9\u5f0f\u53ca\u5176\u4f18\u52a3\u52bf<\/p>\n<\/section>\n<\/section>\n

\n
<\/section>\n<\/section>\n
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\"\u6e05\u534e\u5927\u5b66<\/section>\n<\/section>\n

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2.1<\/strong><\/p>\n<\/section>\n<\/section>\n

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MOFs\u63ba\u5165\u9ad8\u5206\u5b50\u8d28\u5b50\u4ea4\u6362\u819c<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

\u57fa\u4e8e\u73b0\u6709\u8f83\u6210\u719f\u7684\u8d28\u5b50\u4f20\u5bfc\u9ad8\u5206\u5b50\u6750\u6599\uff0c\u63ba\u5165MOFs\u7ec4\u6210\u590d\u5408\u578b\u8d28\u5b50\u4ea4\u6362\u819c\uff0c\u662f\u4e00\u79cd\u53ef\u5feb\u901f\u3001\u6709\u6548\u6539\u5584\u5f53\u524d\u8d28\u5b50\u4ea4\u6362\u819c\u6027\u80fd\u7684\u9014\u5f84\u3002\u5df2\u6709\u5927\u91cf\u5173\u4e8eNafion&MOFs\u590d\u5408\u8d28\u5b50\u4ea4\u6362\u819c\u7684\u62a5\u9053\u3002\u4f8b\u5982\uff0cPatel\u7b49\u5c06\u786b\u9178\u5316\u7684Zr-MOF-808\uff08SZM\uff09\u63ba\u5165Nafion\u5236\u5f97Nafion-SZM\u590d\u5408\u819c\uff0c\u5e76\u6210\u529f\u5e94\u7528\u4e8ePEMFC\u3002SZM\u4e2d\u7684Br\u00f8nsted\u9178\u6027\u4f4d\u70b9\u53ef\u4fdd\u7559\u5145\u8db3\u7684\u6c34\u5206\uff0c\u8fd9\u6709\u52a9\u4e8e\u63d0\u5347\u4f4e\u6e7f\u5ea6\u4e0b\u819c\u7684\u8d28\u5b50\u4f20\u5bfc\u80fd\u529b\u3002\u5728\u76f8\u5bf9\u6e7f\u5ea6\u4e3a35%\u7684\u4f4e\u6e7f\u5ea6\u6761\u4ef6\u4e0b\uff0cMOF\u63ba\u91cf\u4ec5\u4e3a1%\u7684Nafion-SZM\u590d\u5408\u819c\u7684\u4fdd\u6c34\u6027\u80fd\u76f8\u5bf9\u4e8e\u5546\u4e1a\u5316Nafion\u819c\u4fbf\u6709\u6240\u63d0\u9ad8\uff0c\u540c\u65f6\u8d28\u5b50\u7535\u5bfc\u7387\u4e5f\u63d0\u9ad8\u4e8623%\u3002\u56e0\u6b64\uff0c\u642d\u8f7dNafion-SZM\u590d\u5408\u819c\u7684PEMFC\u5728\u4f4e\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5c55\u73b0\u51fa\u4e86\u66f4\u597d\u7684\u6027\u80fd\uff0c\u540c\u65f6\u5728\u4f4e\u589e\u6e7f\u6761\u4ef6\u4e0b\u768424h\u8fde\u7eed\u5f00\u8def\u7535\u538b\u6d4b\u8bd5\u4e2d\uff0c\u5176\u5f00\u8def\u7535\u538b\u964d\u4e5f\u663e\u8457\u66f4\u5c0f\u3002Donnadio\u7b49\u5c06UiO-66\u578bMOF\u4e0eNafion\u5236\u6210\u590d\u5408\u8d28\u5b50\u4ea4\u6362\u819c\uff0c\u5e76\u7814\u7a76\u4e86UiO-66\u7684\u6676\u7c92\u5c3a\u5bf8\u3001\u78fa\u5316\u4e0e\u586b\u5145\u91cf\u5bf9\u4e8e\u6700\u7ec8\u590d\u5408\u819c\u7535\u5bfc\u7387\u53ca\u673a\u68b0\u5f3a\u5ea6\u7684\u5f71\u54cd\u3002\u7ed3\u679c\u8868\u660e\uff0c\u5f53UiO-66\u7684\u5e73\u5747\u7c92\u5f84\u4e3a200nm\uff0c\u586b\u5145\u91cf\u4e3a2%\u65f6\uff0c\u590d\u5408\u819c\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u6700\u9ad8\uff0c\u5728110\u2103\uff0c95%\u76f8\u5bf9\u6e7f\u5ea6\u6761\u4ef6\u4e0b\u5b9e\u73b0\u4e860.207S\/cm\u7684\u9ad8\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u4e14\u4fdd\u6301\u4e86\u590d\u5408\u819c\u7684\u673a\u68b0\u5f3a\u5ea6\u51e0\u4e4e\u4e0d\u4e0b\u964d\u3002\u6b64\u5916\uff0c\u5b9e\u9a8c\u7ed3\u679c\u663e\u793a\uff0c\u5c0f\u7c92\u5f84\uff08\u5e73\u57472nm\uff09\u7684UiO-66\u65e0\u6cd5\u63d0\u5347\u590d\u5408\u819c\u7684\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u4e14\u5728MOF\u7684\u586b\u5145\u91cf\u8f83\u4f4e\u65f6\uff08\u5c0f\u4e8e10%\uff09\uff0c\u78fa\u5316\u540e\u7684SO3<\/sub>H-UiO-66\u76f8\u6bd4\u4e8eUiO-66\u6ca1\u6709\u660e\u663e\u63d0\u5347\u3002\u7c7b\u4f3c\u7684\uff0cKim\u7b49\u5c06\u78f7\u9178\u63ba\u6742\u7684HKUST-1\u578bMOF\u4e0eNafion\u5236\u6210\u590d\u5408\u8d28\u5b50\u4ea4\u6362\u819c\uff0c\u5728MOF\u586b\u5145\u91cf\u4e3a2.5%\u65f6\uff0c\u590d\u5408\u819c\u5c55\u73b0\u51fa\u66f4\u9ad8\u7684\u79bb\u5b50\u4ea4\u6362\u5bb9\u91cf\uff08ion-exchange capacity\uff0cIEC\uff09\u548c\u8d28\u5b50\u7535\u5bfc\u7387\u3002HKUST-1\u4e2d\u7684Cu(\u2161)\u4f7f\u5f97\u914d\u4f4d\u7684\u6c34\u5206\u5b50\u5177\u6709\u8db3\u591f\u7684\u9178\u6027\u6765\u63d0\u4f9b\u8d28\u5b50\uff0c\u540c\u65f6\u6c34\u5206\u5b50\u53ef\u901a\u8fc7\u5438\u9644\/\u89e3\u5438\u8fc7\u7a0b\u8c03\u8282\u6c22\u952e\u7f51\u7edc\uff0c\u7531\u6b64\u63d0\u9ad8\u4e86\u8d28\u5b50\u7535\u5bfc\u7387\u3002\u6b64\u5916\uff0c\u5b9e\u9a8c\u7ed3\u679c\u8fd8\u8868\u660e\uff0c\u5c3d\u7ba1\u5728\u78f7\u9178\u63ba\u6742\u540e\u6750\u6599\u7684\u5438\u6c34\u7387\u7565\u6709\u964d\u4f4e\uff0c\u4f46\u5176IEC\u3001\u8d28\u5b50\u7535\u5bfc\u7387\u548c\u70ed\u7a33\u5b9a\u6027\u5747\u6709\u63d0\u9ad8\u3002\u9664Nafion\u5916\uff0c\u5176\u4ed6\u8d28\u5b50\u4f20\u5bfc\u9ad8\u5206\u5b50\u6750\u6599\u4e5f\u88ab\u5e7f\u6cdb\u7528\u4e8e\u4e0eMOFs\u7ec4\u6210\u590d\u5408\u819c\u3002\u4f8b\u5982\uff0cEren\u7b49\u5206\u522b\u5c06ZIF-8\u548cUiO-66\u578bMOFs\u63ba\u5165\u805a\u82ef\u5e76\u54aa\u5511\uff08polybenzimidazole\uff0cPBI\uff09\u5236\u6210PBI-ZIF8\u3001PBI-UiO66\u590d\u5408\u8d28\u5b50\u4ea4\u6362\u819c\u3002\u4f5c\u8005\u63a2\u7a76\u4e86MOFs\u586b\u5145\u91cf\u57282.5% ~ 10%\u4e4b\u95f4\u53d8\u5316\u65f6\u5bf9\u4e8e\u590d\u5408\u819c\u6027\u80fd\u7684\u5f71\u54cd\uff0c\u7ed3\u679c\u8868\u660e\u5f53\u586b\u5145\u91cf\u4e3a10%\u65f6\uff0cPBI-MOFs\u590d\u5408\u819c\u5177\u6709\u6700\u9ad8\u7684\u8d28\u5b50\u7535\u5bfc\u7387\uff0c\u5728160\u2103\u6761\u4ef6\u4e0b\u590d\u5408\u819c\u7684\u8d28\u5b50\u7535\u5bfc\u7387\u76f8\u5bf9\u4e8e\u7eafPBI\u819c\u63d0\u5347\u4e86\u4e09\u500d\u4ee5\u4e0a\uff0c\u4f46\u540c\u65f6\u51fa\u73b0\u4e86MOFs\u9897\u7c92\u56e2\u805a\uff0c\u6e17\u6c22\u91cf\u4e0a\u5347\uff0c\u590d\u5408\u819c\u673a\u68b0\u5f3a\u5ea6\u4e0b\u964d\u7b49\u95ee\u9898\u3002<\/p>\n

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2.2<\/strong><\/p>\n<\/section>\n<\/section>\n

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MOFs\u4f5c\u4e3a\u8d28\u5b50\u4f20\u5bfc\u7684\u4e3b\u8981\u4ecb\u8d28\u7ec4\u6210MOFs & \u9ad8\u5206\u5b50\u590d\u5408\u819c<\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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2.3<\/strong><\/p>\n<\/section>\n<\/section>\n

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<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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3<\/strong><\/p>\n<\/section>\n<\/section>\n<\/section>\n

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\u7ed3\u8bed\u4e0e\u5c55\u671b<\/strong><\/p>\n<\/section>\n<\/section>\n<\/section>\n<\/section>\n

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