\u4e0a\u6d77\u9ad8\u7814\u9662\u5728\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55<\/strong> \u8fd1\u65e5\uff0c\u4e2d\u56fd\u79d1\u5b66\u9662\u4e0a\u6d77\u9ad8\u7b49\u7814\u7a76\u9662\u9648\u65b0\u5e86\u7814\u7a76\u5458\u56e2\u961f\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u65b9\u9762\u53d6\u5f97\u8fdb\u5c55\uff0c\u5728Applied Catalysis B: Environmental<\/em>\u4e0a\u8fde\u7eed\u53d1\u8868\u4e86\u4e24\u7bc7\u9898\u4e3a\u201cSingle Rh1Co catalyst enabling reversible hydrogenation and dehydrogenation of N-ethylcarbazole for hydrogen storage\u201d (DOI: https:\/\/doi.org\/10.1016\/j.apcatb.2023.122453) \u548c\u201cA highly active Pd clusters hosted by magnesium hydroxide nanosheets promoting hydrogen storage\u201d (DOI: https:\/\/doi.org\/10.1016\/j.apcatb.2023.122793) \u7684\u7814\u7a76\u8bba\u6587\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n \u56fe1 \u53cc\u91d1\u5c5eRh1Co\u50ac\u5316\u5242\u540c\u65f6\u4fc3\u8fdbNEC\u52a0\u6c22\u548c12 H-NEC\u8131\u6c22\u53cd\u5e94\u8def\u5f84\u793a\u610f\u56fe<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n \u6c22\u80fd\u662f\u4e00\u79cd\u6765\u6e90\u4e30\u5bcc\u3001\u7eff\u8272\u4f4e\u78b3\u3001\u5e94\u7528\u5e7f\u6cdb\u7684\u4e8c\u6b21\u80fd\u6e90\uff0c\u53d1\u5c55\u6c22\u80fd\u5bf9\u6784\u5efa\u6e05\u6d01\u4f4e\u78b3\u5b89\u5168\u9ad8\u6548\u7684\u80fd\u6e90\u4f53\u7cfb\u3001\u5b9e\u73b0\u78b3\u8fbe\u5cf0\u78b3\u4e2d\u548c\u76ee\u6807\uff0c\u5177\u6709\u91cd\u8981\u610f\u4e49\u3002\u7136\u800c\uff0c\u6c22\u6c14\u7684\u5b89\u5168\u9ad8\u6548\u50a8\u5b58\u548c\u8fd0\u8f93\u6781\u5927\u5730\u9650\u5236\u4e86\u6c22\u80fd\u7684\u53d1\u5c55\u3002\u76ee\u524d\u4f20\u7edf\u7684\u52a0\u6c22\u50ac\u5316\u5242\u5b58\u5728\u8d35\u91d1\u5c5e\u7528\u91cf\u9ad8\u3001\u53cd\u5e94\u6e29\u5ea6\u9ad8\u7b49\u7f3a\u70b9\uff0c\u4e0d\u5229\u4e8e\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u5728\u5b9e\u9645\u4e2d\u7684\u5e94\u7528\u3002\u56e0\u6b64\uff0c\u63a2\u7d22\u6e29\u548c\u6761\u4ef6\u4e0b\u4f4e\u6210\u672c\u7684\u9ad8\u6548\u50ac\u5316\u5242\u662f\u4e00\u4e2a\u4e9f\u5f85\u89e3\u51b3\u7684\u95ee\u9898\u3002 <\/span><\/p>\n \u9488\u5bf9\u6b64\u95ee\u9898\uff0c\u8be5\u56e2\u961f\u5206\u522b\u62a5\u9053\u4e86\u4e00\u79cdRh\u5355\u539f\u5b50\u4e0eCo\u7eb3\u7c73\u9897\u7c92\uff08NP\uff09\u7ed3\u5408\u7684Rh1Co\u50ac\u5316\u5242\uff0c\u540c\u65f6\u4fc3\u8fdb\u4e86NEC\uff08N-\u4e59\u57fa\u5494\u5511\uff09\u52a0\u6c22\u548c12 H-NEC\u7684\u8131\u6c22\uff0c\u5e76\u5b9e\u73b0\u4e86\u53ef\u9006\u6c22\u5438\u6536\u548c\u91ca\u653e\u7684\u591a\u4e2a\u5faa\u73af\uff08\u56fe1\uff09\u3002\u800c\u4e14\uff0c\u8be5\u50ac\u5316\u5242\u53ef\u572890\u2103\u7684\u76f8\u5bf9\u6e29\u548c\u6761\u4ef6\u4e0b\u5c06NEC\u5b8c\u5168\u52a0\u6c22\u3002\u53e6\u5916\u5f00\u53d1\u4e86\u4e00\u79cd\u4e8c\u7ef4-\u6c22\u6c27\u5316\u9541\u7eb3\u7c73\u7247\u8d1f\u8f7d Pd\u50ac\u5316\u5242\uff0c\u5728\u91d1\u5c5e\u8d1f\u8f7d\u91cf\u4ec5\u4e3a 0.5 wt%\u7684\u60c5\u51b5\u4e0b\uff0c12H-NEC \u7684\u8f6c\u5316\u7387\u8fbe 100%\uff0c\u8131\u6c22\u91cf\u8fbe 5.72 wt%\uff08\u56fe2\uff09\uff0c\u8fd1\u4e4e\u8fbe\u5230\u4e86\u5176\u7406\u8bba\u50a8\u6c22\u503c\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n \u56fe2. \u4e8c\u7ef4-\u6c22\u6c27\u5316\u9541\u7eb3\u7c73\u7247\u8d1f\u8f7d Pd\u50ac\u5316\u5242\u7528\u4e8eN-\u4e59\u57fa\u5494\u5511\uff08NEC\uff09\u8131\u6c22\u53cd\u5e94<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n \u8fd1\u5e74\u6765\u8be5\u7814\u7a76\u56e2\u961f\u805a\u7126\u4e8e\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u9886\u57df\u50ac\u5316\u5242\u7684\u5de5\u4f5c\uff1a\u901a\u8fc7\u8d1f\u8f7d\u5728*BEA\u5206\u5b50\u7b5b\u4e0a\u7684Ru\u5355\u539f\u5b50\u50ac\u5316\u5242\u7528\u4e8eLOHCs\uff08\u4e3b\u8981\u4e3aNEC\uff09\u4e0a\u7684\u50a8\u6c22\uff08Applied Catalysis B: Environmental, 2022,319, 121958\uff09\u3002\u4e0e\u5e38\u89c4Ru\/Al2<\/span><\/sub>O3<\/span><\/sub>\u50ac\u5316\u5242\u76f8\u6bd4\uff0c\u539f\u5b50\u5206\u6563\u7684Ru\u4f4d\u70b9\u548c*BEA\u5206\u5b50\u7b5b\u4e0a\u76f8\u90bb\u9178\u4f4d\u70b9\u534f\u540c\u6d3b\u5316\u6c22\uff0c\u901a\u8fc7\u6c22\u6ea2\u6d41\u4f5c\u7528\uff0c\u53ef\u5728\u8f83\u4f4e\u6e29\u5ea6\u4e0b\u5b9e\u73b0NEC\u7684\u6c22\u5316\uff1b\u5236\u5907\u4e86\u53cc\u91d1\u5c5ePd-Rh\u50ac\u5316\u5242\uff0c\u5229\u7528\u53cc\u91d1\u5c5e\u7eb3\u7c73\u7c92\u5b50\u7684\u534f\u540c\u6548\u5e94\uff0c\u540c\u65f6\u589e\u5f3a\u4e86NEC\u7684\u52a0\u6c22\u548c12-NEC\u7684\u8131\u6c22\u6027\u80fd\uff08Chemical Engineering Journal, 2021, 421\uff0c127781\uff09\uff1b\u9488\u5bf9Rh\u8d35\u91d1\u5c5e\u542b\u91cf\u9ad8\u7684\u95ee\u9898\uff0c\u5236\u5907\u4e860.1%Rh-Ni\u53cc\u91d1\u5c5e\u50ac\u5316\u5242\u7528\u4e8eNEC\u7684\u52a0\u6c22\uff0c\u5927\u5927\u964d\u4f4e\u4e86\u50ac\u5316\u5242\u7684\u5236\u5907\u6210\u672c\uff08ACS Sustainable Chem. Eng. 2021, 5260-5267\uff09\u3002\u6b64\u6b21\u7684\u7814\u7a76\u5728\u524d\u5e8f\u57fa\u7840\u4e0a\u4f7f\u5f97\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u53cd\u5e94\u6761\u4ef6\u66f4\u6e29\u548c\u5316\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n \u672c\u7814\u7a76\u5de5\u4f5c\u4e3a\u8d1f\u8f7d\u578b\u91d1\u5c5e\u50ac\u5316\u5242\u5728\u6e29\u548c\u6761\u4ef6\u4e0b\u50ac\u5316\u6709\u673a\u6db2\u4f53\u50a8\u6c22\u65b9\u9762\u63d0\u4f9b\u4e86\u4e00\u79cd\u6709\u6548\u7b56\u7565\u3002\u8bba\u6587\u7684\u7b2c\u4e00\u4f5c\u8005\u662f\u6211\u9662\u535a\u58eb\u7814\u7a76\u751f\u845b\u4e3d\u971e\uff0c X-\u5c04\u7ebf\u5438\u6536\u8868\u5f81\u901a\u8fc7\u4e0e\u6211\u9662\u4e0a\u6d77\u5149\u6e90\u674e\u70af\u7814\u7a76\u5458\u5728BL11B\u7ebf\u7ad9\u5f00\u5c55in-house\u7814\u7a76\u5b8c\u6210\u3002\u8be5\u7814\u7a76\u5de5\u4f5c\u5f97\u5230\u4e86\u56fd\u5bb6\u81ea\u7136\u79d1\u5b66\u57fa\u91d1\u548c\u56fd\u5bb6\u91cd\u70b9\u7814\u53d1\u8ba1\u5212\u7684\u8d44\u52a9\u3002<\/span><\/p>\n<\/section>\n<\/section>\n<\/section>\n
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