{"id":8041,"date":"2022-09-17T03:38:51","date_gmt":"2022-09-17T03:55:42","guid":{"rendered":"https:\/\/www.htech360.com\/?p=8041"},"modified":"2022-09-17T11:55:44","modified_gmt":"2022-09-17T03:55:44","slug":"40c3f1c24f","status":"publish","type":"post","link":"https:\/\/www.htech360.com\/a\/8041","title":{"rendered":"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406"},"content":{"rendered":"
\n

\u6c22\u773c\u6240\u89c1\u5bfb\u627e\u6709\u7f18\u7684\u6c22\u80fd\u4eba\uff0c\u6709\u7f18\u4e4b\u4eba\u53ef\u6dfb\u52a0\u5fae\u4fe1\u201czen13480834343\u201d<\/span><\/strong>    <\/span><\/p>\n

<\/mp-common-profile><\/section>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/p>\n


<\/p>\n

HER\u662f\u7814\u7a76\u6700\u5e7f\u6cdb\u7684\u7535\u5316\u5b66\u53cd\u5e94\u4e4b\u4e00\uff0c\u7531\u4e8e\u5176\u76f8\u5bf9\u7b80\u5355\u548c\u76f4\u63a5\u7684\u5de5\u4e1a\u76f8\u5173\u6027\uff0c\u4e0d\u4ec5\u5728\u6c34\u7535\u89e3\u4e2d\uff0c\u800c\u4e14\u4e5f\u51fa\u73b0\u5728\u6c2f\u78b1\u5de5\u827a\u4e2d\u3002\u4e0eOER\u548cORR\u7684\u7f13\u6162\u52a8\u529b\u5b66\u76f8\u6bd4\uff0c\u8d35\u91d1\u5c5e(\u94c2\u65cf\u91d1\u5c5e\uff0cPGM)\u5728\u7535\u6781\u4e0a\u7684HER\u7684\u52a8\u529b\u5b66\u8981\u5feb\u5f97\u591a\uff0c\u56e0\u6b64\u5728\u51e0\u5341\u6beb\u4f0f\u7684\u8fc7\u7535\u4f4d\u4e0b\uff0c\u5b9e\u9645\u4ea7\u751f\u5927\u4e8e1A\/cm2<\/span>\u7535\u6d41\u5bc6\u5ea6\u662f\u53ef\u80fd\u7684\uff0c\u552f\u4e00\u7684\u4f8b\u5916\u662f\u78b1\u6027\u4ecb\u8d28\u4e2d\u7684HER(\u5373\u4f7f\u5728PGM\u8868\u9762\u4e5f\u4f1a\u4f8b\u5916)\u3002\u65e8\u5728\u9610\u660e\u91d1\u5c5e\u57fa\u8868\u9762\u4e0a\u7684HER\u673a\u5236\u96c6\u4e2d\u5728\u954d\u4e0a<\/span>\u7684\u7b2c\u4e00\u4e2a\u7814\u7a76\uff0c\u5927\u7ea6\u65f6\u95f4\u53ef\u4ee5\u8ffd\u6eaf\u5230\u5341\u4e5d\u4e16\u7eaa\u4e94\u5341\u5e74\u4ee3\u5e74\u4ee3\u65e9\u671f\u3002HER\u7684\u53cd\u5e94\u987a\u5e8f\u9996\u5148\u662f\u5728\u9178\u6027\u6761\u4ef6\u4e0b(M-H+)\u5438\u9644\u8d28\u5b50\uff0c\u6216\u5728\u4e2d\u6027\u6216\u78b1\u6027\u73af\u5883\u4e0b(M-HOH)\u5438\u9644\u6c34\u5206\u5b50\/\u8d28\u5b50\uff0c\u7136\u540e\u8fd8\u539f\u5f62\u6210M-H *(\u5728\u5316\u5b66\u5438\u9644\u6c34\u8fd8\u539f\u7684\u60c5\u51b5\u4e0b\u91ca\u653eOH-)\u3002<\/span>\u4ece\u8fd9\u91cc\u5f00\u59cb\uff0c\u53ef\u4ee5\u533a\u5206\u4e24\u4e2a\u53ef\u80fd\u7684\u540e\u7eed\u6b65\u9aa4:(1)\u5316\u5b66\u5438\u9644\u7684Had\u4e0e\u53e6\u4e00\u4e2a\u5316\u5b66\u5438\u9644\u7684H*\u7ed3\u5408\uff0c\u79f0\u4e3aTafel\u6b65\u9aa4\uff0c\u5bfc\u81f4H2,ad\u7684\u5316\u5b66\u89e3\u6790\uff1b\u6216(2)\u5316\u5b66\u5438\u9644\u7684\u8d28\u5b50\u4e0e\u6eb6\u6db2\u4e2d\u7684\u53e6\u4e00\u4e2a\u8d28\u5b50\u6216\u6c34\u5206\u5b50\u53d1\u751f\u7535\u5316\u5b66\u53cd\u5e94\uff0c\u79f0\u4e3aHeyrovsky\u6b65\u9aa4\uff0c\u63a5\u7740\u662f\u8fdb\u4e00\u6b65\u7684\u7535\u5316\u5b66\u653e\u7535\u548cH2\u7684\u89e3\u6790\u3002<\/span>\u524d\u4e00\u4e2a\u6b65\u9aa4\u5e8f\u5217\u5bf9\u5e94\u4e8eVolmer-Tafel\u673a\u7406\uff0c\u800c\u540e\u8005\u88ab\u79f0\u4e3aVolmer-Heyrovsky\u673a\u7406\u3002<\/span><\/span><\/section>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/p>\n

(c)\u5728\u9178\u6027(\u84dd\u8272)\u6216\u78b1\u6027(\u7ea2<\/span>\u8272)\u6761\u4ef6\u4e0b\u7535\u6781\u8868\u9762\u7684Volmer-Tafel HER\u673a\u5236\u3002<\/span>
<\/p>\n

(d) HER\u7684Volmer-Heyrovsky\u673a\u5236\u3002<\/span><\/p>\n

\u4e0a\u56fe(c)\u548c(d)\u8bf4\u660e\u4e86\u9178\u6027\u548c\u78b1\u6027\u6761\u4ef6\u4e0bHER\u7684\u4e24\u79cd\u9014\u5f84\uff0c\u5206\u522b\u662fVolmer-Tafel\u673a\u7406\u548cVolmer-Heyrovsky\u673a\u7406\u3002\u8fd9\u4e24\u79cd\u9014\u5f84\u90fd\u662f\u4eceVolmer<\/span>\u6b65\u9aa4\u5f00\u59cb\u7684\uff0c\u5728\u8fd9\u4e00\u6b65\u9aa4\u4e2d\uff0c\u4ece\u7535\u6781\u4e0a\u7684\u7535\u5b50\u8f6c\u79fb\u4e0e\u50ac\u5316\u5242\u4e0a\u7684\u8d28\u5b50\u5438\u9644\u76f8\u7ed3\u5408\uff0c\u5f62\u6210\u5438\u9644\u7684H\u539f\u5b50\uff0c<\/span><\/p>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/section>\n
\u6c34\u5408\u6c22\u79bb\u5b50(H<\/span>3<\/span>O+)\u548c\u6c34\u5206\u5b50\u5206\u522b\u662f\u9178\u6027\u548c\u78b1\u6027\u7535\u89e3\u8d28\u4e2d\u8d28\u5b50\u7684\u6765\u6e90\u3002\u63a5\u4e0b\u6765\uff0c\u5728Volmer-Tafel\u673a\u5236\u4e2d\uff0cTafel\u6b65\u9aa4\u5c06\u76f8\u90bb\u4f4d\u70b9\u4e0a\u7684\u4e24\u4e2aH*\u7ed3\u5408\u5f62\u6210H<\/span>2<\/span>\uff0c\u5373:<\/span><\/section>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/p>\n

\u5728Volmer-Heyrovsky\u673a\u5236\u7684Heyrovsky\u6b65\u9aa4\u4e2d\uff0cH<\/span>2<\/span>\u662f\u901a\u8fc7H*\u539f\u5b50\u4e0e\u8d28\u5b50(\u5728\u9178\u6027\u73af\u5883\u4e2d)\u548c\u6c34\u5206\u5b50(\u5728\u78b1\u6027\u73af\u5883\u4e2d)\u7684\u76f4\u63a5\u76f8\u4e92\u4f5c\u7528\u5f62\u6210\u7684\u3002<\/span><\/p>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/section>\n
\u4e0b\u56fe\u65b9\u6848\u663e\u793a\u4e86\u5728\u9178\u6027\u4f53\u7cfb\u4e2d\u6839\u636e\u4e24\u79cd\u673a\u5236\u8fdb\u884c\u6790\u6c22\u7684\u53cd\u5e94\u6b65\u9aa4\uff0c\u4e00\u79cd\u6216\u53e6\u4e00\u79cdHER\u673a\u5236\u7684\u53d1\u751f\u53d6\u51b3\u4e8e\u64cd\u4f5c\u53c2<\/span>\u6570\uff0c\u5305\u62ecpH\u503c\u3001\u7535\u6781\u7535\u4f4d\u4ee5\u53ca\u6240\u8003\u8651\u7684\u7535\u6781\u7684\u6027\u8d28\u548c\u7ed3\u6784\u8fc4<\/span>\u4eca\u4e3a\u6b62\uff0c\u954d\u4ecd\u7136\u662f\u78b1\u6027\u73af\u5883\u4e0b\u6700\u53d7\u6b22\u8fce\u7684HER(\u548cHOR)\u975e\u8d35\uff08\u8d31\uff09\u91d1\u5c5e\uff0c\u5e76\u53d7\u5230\u7814\u7a76\u56e2\u4f53\u7684\u5e7f\u6cdb\u5173\u6ce8\u3002<\/span><\/span><\/section>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/p>\n

\uff08<\/span>\u5907\u6ce8\uff1a\u9178\u6027\u73af\u5883\u4e2d\u7684\u6790\u6c22\u673a\u7406<\/span>\uff09<\/span><\/p>\n


<\/span><\/p>\n

\u5982\u4e0a\u56fe\u6240\u793a\uff0c\u6211\u4eec\u5f88\u5bb9\u6613\u7406\u89e3M-H *\u952e\u5f3a\u5ea6\u4f1a\u5f71\u54cd\u91d1\u5c5e\u5bf9HER\u7684\u50ac\u5316\u6d3b\u6027\u3002\u4e00\u65b9\u9762\uff0c\u9700\u8981\u5927\u91cf\u7684\u5f3a\u5ea6\u6765\u652f\u6301M-H *\u952e\u7684\u5f62\u6210\uff0c\u8fd9\u662f\u542f\u52a8\u53cd\u5e94\u5e8f\u5217\u7684\u7b2c\u4e00\u6b65(Volmer)\u3002\u53e6\u4e00\u65b9\u9762\uff0c\u592a\u5f3a\u7684M-H\u952e\u4f1a\u4ea7\u751f\u53cd\u6548\u679c\uff0c\u56e0\u4e3a\u5316\u5b66\u5438\u9644\u7684\u4e2d\u95f4\u4f53\u6216\u4ea7\u7269\u79cd\u7c7b\u4e0d\u4f1a\u8f7b\u6613\u4ece\u8868\u9762\u91ca\u653e\u51fa\u6765\uff0c\u4ece\u800c\u9020\u6210\u8868\u9762\u963b\u585e\u6548\u5e94\u3002\u8fd9\u662f\u8fd8\u539fNi\u8868\u9762\u7684\u60c5\u51b5\uff0c\u5b83\u4e0eH<\/span>ad<\/span>\u7ed3\u5408\u5f97\u592a\u5f3a\u70c8\uff0c\u800c\u6c27\u5316Ni\u8868\u9762\u5448\u73b0\u4e2d\u95f4\u4f53\uff0c\u56e0\u6b64\u66f4\u201c\u4f18\u5316\u201d\u7684Ni-H\u952e\u5f3a\u5ea6\uff0c\u6709\u5229\u4e8e\u5feb\u901fHER\/HOR\u3002\u7814\u7a76\u8bc1\u5b9e\uff0c\u50ac\u5316\u5242\u5bf9HER\u7684\u50ac\u5316\u6d3b\u6027\u4e0e\u50ac\u5316\u5242\u8868\u9762\u4e0e\u5438\u9644\u6c22\u76f8\u4e92\u4f5c\u7528\u7684\u5f3a\u5ea6\u6709\u5173\u3002\u5728\u8fc7\u7535\u4f4d\u8f83\u4f4e\u65f6(HER\u901a\u5e38\u53d1\u751f\u4e8e\u6b64)\uff0c\u7535\u6d41-\u7535\u538b\u66f2\u7ebf\u7684\u659c\u7387\u4e0e\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6j0\u6210\u6b63\u6bd4\u3002\u5728\u5927\u91cf\u7684\u5b9e\u9a8c\u7814\u7a76\u4e2d\u5df2\u7ecf\u62a5\u9053\u4e86\u5728\u9178\u6027\u4ecb\u8d28\u4e2d\u7eaf\u91d1\u5c5e\u4e0aHER\u7684\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u6839\u636e\u91d1\u5c5e\u6c22\u952e\u5f3a\u5ea6\u7ed8\u5236\u8fd9\u4e9b\u503c\u663e\u793a\u4e86\u4e00\u79cd\u88ab\u79f0\u4e3a\u201c\u706b\u5c71\u201d\u66f2\u7ebf\uff08\u4e0b\u56fe\uff09\u7684\u7279\u5f81\u884c\u4e3a\uff0c\u5e76\u57fa\u4e8e\u8428\u5df4\u8482\u5c14\u539f\u7406\u9884\u671f\uff1aHER\u6d3b\u6027\u589e\u52a0\u5230\u4e2d\u7b49\u952e\u5f3a\u5ea6\uff08Pt\u3001Rh\u3001Ir\uff09\u65f6\u83b7\u5f97\u7684\u5cf0\u503c\uff0c\u7136\u540e\u518d\u6b21\u671d\u7740\u66f4\u9ad8\u7684\u952e\u5f3a\u5ea6\u964d\u4f4e\u3002\u503c\u5f97\u6ce8\u610f\u7684\u662f\uff0cTrasatti\u706b\u5c71\u4ec5\u9002\u7528\u4e8e\u9178\u6027\u4ecb\u8d28\uff0c\u4e14\u9700\u8981\u5bf9Pt\u8fdb\u884c\u4ea4\u6362\u7535\u6d41\u5bc6\u5ea6\u6821\u6b63\u3002<\/span><\/section>\n

\"\u7535\u89e3\u6c34\u4e2d\u6790\u6c22\u53cd\u5e94\uff08HER\uff09\u7684\u57fa\u672c\u673a\u7406\"<\/p>\n

\u56fe\u7247\u8bf4\u660e\uff1a<\/span><\/strong>
<\/p>\n

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